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• W2137878147 abstract "The calcium-doped manganates, Pr1−xCaxMnO3 (x=0.39, 0.46, 0.70, 0.76), were synthesized as cube-shaped crystalline phases under mild hydrothermal conditions for the first time. The crystals could be grown in one step from solutions of metal salts and potassium hydroxide at temperatures ∼240 °C, and found to adopt perovskite-like structure (space group Pbnm). Samples were characterized by powder X-ray diffraction, scanning electron microscopy, inductively coupled plasma analysis and variable temperature dc/ac magnetic susceptibility. The studies indicate that formation of the materials is dependent on the alkalinity and composition of the initial reaction mixtures. The magnetic properties show spin-glass-like behavior due to competing ferromagnetic (FM) and antiferromagnetic (AFM) exchange interactions in Pr1−xCaxMnO3 with x=0.39, 0.46." @default.
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• W2137878147 date "2007-01-01" @default.
• W2137878147 modified "2023-10-07" @default.
• W2137878147 title "Mild hydrothermal synthesis and magnetic properties of the manganates Pr1−xCaxMnO3" @default.
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• W2137878147 doi "https://doi.org/10.1016/j.jssc.2006.09.029" @default.
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