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- W2137940269 abstract "Reaction of AlMe3 with [(tBu)2Ga(μ-OH)]3 or Ph3EOH (E = Sn, Pb) yields catalytically active MAO, [MeAlO]n, along with (tBu)2GaMe and Ph3EMe, respectively, in contrast, the reaction with Ph3EOH (E = C, Si, Ge) yields [Me2Al(μ-OEPh3)]2; the formation of MAO is proposed to occur via hydroxide exchange and the formation of unstable [Me2Al(μ-OH)]n; the propensity towards alkane elimination versus hydroxide exchange is controlled by the relative Brønsted acidity of the main group hydroxide." @default.
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- W2137940269 date "2001-01-01" @default.
- W2137940269 modified "2023-10-09" @default.
- W2137940269 title "Reaction of trimethylaluminium with main group hydroxides: a non-hydrolysis route to methylalumoxane†" @default.
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- W2137940269 doi "https://doi.org/10.1039/b104578b" @default.
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