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• W2138017861 abstract "The synthesis and characterization of ruthenium mononuclear complexes containing NO bidentate ligands are reported. The complexes cis-[RuII(bpy)2L](PF6)n (1a–c), [RuIIICl(L)2(H2O)] (2a–b) and [RuIIICl2(L)2]Cl (2c) were prepared by the reaction of cis-[RuIICl2(bpy)2]·2H2O (bpy = 2,2′-bipyridine) and/or RuCl3·nH2O with the Ligands: 2-aminophenol (2-aph), 8-hydroxyquinoline (8-hq) and 4-aminoantipyrine (4-apy). These complexes were characterized by elemental analysis, spectroscopic (IR, UV–Vis, 1H NMR, ESR) and magnetic susceptibility measurements. The ligand field parameters, Δo (splitting parameter), B (Racah parameter of interelectronic repulsion), and β (nephelauxetic ratio) were calculated. The redox properties were also investigated electrochemically by cyclic voltammetry. The complexes cis-[RuII(bpy)2(8-hq)](PF6)2 (1b) and [RuIIICl(8-hq)2(H2O)] (2b) have been investigated in conjunction with N-methylmorpholine-N-oxide (NMO) as co-oxidant for the catalytic dehydrogenation of benzyl amine, p-methyl benzylamine and p-nitrobenzylamine to their respective nitriles." @default.
• W2138017861 created "2016-06-24" @default.
• W2138017861 creator A5016917468 @default.
• W2138017861 creator A5035448644 @default.
• W2138017861 date "2014-10-01" @default.
• W2138017861 modified "2023-09-27" @default.
• W2138017861 title "Synthesis, spectral and catalytic dehydrogenation studies of ruthenium complexes containing NO bidentate ligands" @default.
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• W2138017861 doi "https://doi.org/10.1016/j.saa.2014.04.132" @default.
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