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• W2138045176 abstract "The homogeneous hydrogenation of methyl (Z) and (E)-2-phenylethene-carboxylate [(1) and (2)] in the presence of a platinum—tin catalyst has been investigated. Hydrogenation of (1) was accompanied by partial isomerization to give (2). Tracer experiments with deuterium revealed the steric course of the transfer steps. Transfer of the first deuterium atom to coordinated (1) is considered to proceed stepwise via a zwitterionic intermediate, resulting in a mixture of the diastereomeric 1-methoxycarbonyl-2-deutero-2-phenylethyl complexes. The same reaction with hydrogen proceeds suprafacially. Protonolytic cleavage of the alkyl complexes proceeds non-stereospecifically." @default.
• W2138045176 created "2016-06-24" @default.
• W2138045176 creator A5048387569 @default.
• W2138045176 creator A5082439998 @default.
• W2138045176 date "1976-07-01" @default.
• W2138045176 modified "2023-09-26" @default.
• W2138045176 title "Platinum—tin catalyzed homogeneous hydrogenation. The steric course of the hydrogen-transfer steps" @default.
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• W2138045176 doi "https://doi.org/10.1016/0304-5102(76)85016-x" @default.
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