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- W2138166873 abstract "In this work we have analyzed the conditions leading to a kinetic demixing of species in ceramics during cooling. Estimation of cation redistributions during cooling in a model material shows that a segregation maximum could be observed near surfaces at an intermediate cooling rate. This result is explained on the basis of two competing effects: the cation redistribution kinetics and the driving force of matter transport related to the cooling rate. Experimental results obtained with titanium and magnesium‐doped α‐alumina single crystals show that the segregation of titanium increases when the oxygen partial pressure increases and when the cooling rate and annealing temperature decrease. The opposite effect is generally observed for magnesium and other detected impurities. Complementary characterizations show that these kinetic reactions are also significantly influenced by the impurities present in the material." @default.
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- W2138166873 date "1995-09-01" @default.
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- W2138166873 title "Kinetic Demixing of Solute Cations in Alumina Single Crystals during Cooling" @default.
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- W2138166873 doi "https://doi.org/10.1111/j.1151-2916.1995.tb08663.x" @default.
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