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- W2138415993 abstract "The paper contains the results of natural film experiments carried out on inland waters in the Dead Vistula (Martwa Wisla) catchment area during 1999–2002 using the integrated Langmuir trough-Wilhelmy plate system,which ‘cuts out’ an undisturbed film-covered area without any physicochemical sample processing. The static film parameters result from the generalized scaling procedures applied to the surface pressure-area isotherms. They appear to correspond well to observations of the film composition (Alim, MW , Eisoth),film solubility and the miscibility of its components (via R, ∆Sc and y factors),and surface concentration ( πeq, Γeq). A novel approach is presented for the adsorption dynamics on the basis of the mixed kinetic-diffusion model and analyses of the dynamic surface pressure plots,which leads to the determination of the effective relative diffusion coefficient Deff/D and activation energy barrier Ea/RT . There is reason to believe that certain classes of film-forming components or ‘end-members’ may dominate the static and dynamic surface properties. Some of these substances can be used as" @default.
- W2138415993 created "2016-06-24" @default.
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- W2138415993 date "2003-09-01" @default.
- W2138415993 modified "2023-09-23" @default.
- W2138415993 title "Adsorptive properties of natural water surfactant films. Dead Vistula catchment water studies" @default.
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