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- W2138450101 abstract "Forward-directed NO molecules with large translational energies are formed upon exposure of an O-covered Ru(0001) surface to a nitrogen ($mathrm{N}+{mathrm{N}}_{2}$) beam. This is an unequivocal experimental demonstration of the Eley-Rideal reaction for a ``heavy'' (i.e., nonhydrogenated) neutral system. The time dependence of prompt NO formation exhibits an exceptionally fast decay as a consequence of shifting reaction pathways and probabilities over the course of the exposure. Prompt production shuts down as the O coverage decreases due to competition from more favorable Eley-Rideal production of ${mathrm{N}}_{2}$." @default.
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- W2138450101 date "2014-07-29" @default.
- W2138450101 modified "2023-09-26" @default.
- W2138450101 title "Eley-Rideal Reactions with N Atoms at Ru(0001): Formation of NO and<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>N</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W2138450101 doi "https://doi.org/10.1103/physrevlett.113.053201" @default.
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