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- W2138502011 abstract "Thermoplastic and addition curing polyimides based on non-coplanar 2,2',6,6'-tetrarnethylbenzidine (TMBZ) were prepared and investigated. The TMBZ based thermoplastic polyimides displayed high T g values, enhanced solubility and excellent thermal stability. These high-mnolecular-weight polyimides could be either cast into optically transparent thin films or spun into fibres. The addition curing polyimides based on TMBZ exhibited higher T g values than the corresponding PMR-1I type polyimides, due to the increased rotational barrier created by the substituents on the biphenyl moiety. However, the methyl substituents on the TMBZ inherently lowered the thermo-oxidative stability of TMBZ based polyimides, relative to the corresponding PMR-II type polyimides." @default.
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- W2138502011 date "1995-02-01" @default.
- W2138502011 modified "2023-09-24" @default.
- W2138502011 title "Polyimides based on 2,2',6,6'-tetramethylbenzidine" @default.
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- W2138502011 doi "https://doi.org/10.1088/0954-0083/7/1/007" @default.
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