FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2138659763> ?p ?o ?g. }

• W2138659763 endingPage "6202" @default.
• W2138659763 startingPage "6193" @default.
• W2138659763 abstract "Abstract We report here the formation of a long‐lived charge‐separated state of a self‐assembled donor–acceptor tetrad, formed by axial coordination of a fulleropyrrolidine appended with an imidazole coordinating ligand (C 60 Im) to the zinc center of a subphthalocyanine–triphenylamine–zinc porphyrin (SubPc–TPA–ZnP), as a charge‐stabilizing antenna reaction center mimic in toluene. The subphthalocyanine and triphenylamine entities, with their high‐energy singlet states, act as an energy‐transferring antenna unit to produce a singlet zinc porphyrin. The formation constant for the self‐assembled tetrad was determined to be 1.0×10 4 M −1 , suggesting a moderately stable complex formation. The geometric and electronic structures of the covalently linked SubPc–TPA–ZnP triad and self‐assembled SubPc–TPA–ZnP:C 60 Im tetrad were examined by using an ab initio B3LYP/6‐31G method. The majority of the highest occupied frontier molecular orbital was found over the ZnP and TPA entities, whereas the lowest unoccupied molecular orbital was located over the fullerene entity, suggesting the formation of the radical‐ion pair (SubPc–TPA–ZnP .+ :C 60 Im .− ). The redox measurements revealed that the energy level of the radical‐ion pair in toluene is located lower than that of the singlet and triplet states of the zinc porphyrin and fullerene entities. The femtosecond transient absorption measurements revealed fast charge separation from the singlet porphyrin to the coordinated C 60 Im with a lifetime of 1.1 ns. Interestingly, slow charge recombination (1.6×10 5 s −1 ) and the long lifetime of the charge‐separated state (6.6 μs) were obtained in toluene by utilizing the nanosecond transient measurements." @default.
• W2138659763 created "2016-06-24" @default.
• W2138659763 creator A5062868414 @default.
• W2138659763 creator A5064037442 @default.
• W2138659763 creator A5066193981 @default.
• W2138659763 creator A5083742579 @default.
• W2138659763 creator A5090301764 @default.
• W2138659763 date "2010-05-25" @default.
• W2138659763 modified "2023-10-18" @default.
• W2138659763 title "Supramolecular Tetrad of Subphthalocyanine-Triphenylamine-Zinc Porphyrin Coordinated to Fullerene as an “Antenna-Reaction-Center” Mimic: Formation of a Long-Lived Charge-Separated State in Nonpolar Solvent" @default.
• W2138659763 cites W11476871 @default.
• W2138659763 cites W1520363451 @default.
• W2138659763 cites W1530818404 @default.
• W2138659763 cites W1916260872 @default.
• W2138659763 cites W1964408943 @default.
• W2138659763 cites W1966624508 @default.
• W2138659763 cites W1968609032 @default.
• W2138659763 cites W1969170278 @default.
• W2138659763 cites W1971597127 @default.
• W2138659763 cites W1974560925 @default.
• W2138659763 cites W1976870657 @default.
• W2138659763 cites W1977265934 @default.
• W2138659763 cites W1978085924 @default.
• W2138659763 cites W1984090726 @default.
• W2138659763 cites W1984589180 @default.
• W2138659763 cites W1985291304 @default.
• W2138659763 cites W1986400372 @default.
• W2138659763 cites W1987576577 @default.
• W2138659763 cites W1989217436 @default.
• W2138659763 cites W1996218377 @default.
• W2138659763 cites W2001929588 @default.
• W2138659763 cites W2002742052 @default.
• W2138659763 cites W2006883333 @default.
• W2138659763 cites W2011344355 @default.
• W2138659763 cites W2014394792 @default.
• W2138659763 cites W2015073555 @default.
• W2138659763 cites W2016187188 @default.
• W2138659763 cites W2020483135 @default.
• W2138659763 cites W2023544689 @default.
• W2138659763 cites W2024471326 @default.
• W2138659763 cites W2031904472 @default.
• W2138659763 cites W2035025222 @default.
• W2138659763 cites W2035427507 @default.
• W2138659763 cites W2040006466 @default.
• W2138659763 cites W2041953696 @default.
• W2138659763 cites W2042605418 @default.
• W2138659763 cites W2043420501 @default.
• W2138659763 cites W2043836941 @default.
• W2138659763 cites W2044400760 @default.
• W2138659763 cites W2045518670 @default.
• W2138659763 cites W2046133238 @default.
• W2138659763 cites W2050081248 @default.
• W2138659763 cites W2051240069 @default.
• W2138659763 cites W2052752040 @default.
• W2138659763 cites W2054374618 @default.
• W2138659763 cites W2054377197 @default.
• W2138659763 cites W2054969693 @default.
• W2138659763 cites W2058351727 @default.
• W2138659763 cites W2062082636 @default.
• W2138659763 cites W2063791523 @default.
• W2138659763 cites W2069506896 @default.
• W2138659763 cites W2069560513 @default.
• W2138659763 cites W2069981101 @default.
• W2138659763 cites W2070227590 @default.
• W2138659763 cites W2070963935 @default.
• W2138659763 cites W2071254888 @default.
• W2138659763 cites W2075134695 @default.
• W2138659763 cites W2075731402 @default.
• W2138659763 cites W2078676357 @default.
• W2138659763 cites W2079085674 @default.
• W2138659763 cites W2084135940 @default.
• W2138659763 cites W2086915866 @default.
• W2138659763 cites W2092072232 @default.
• W2138659763 cites W2094346859 @default.
• W2138659763 cites W2095216354 @default.
• W2138659763 cites W2098883905 @default.
• W2138659763 cites W2100350057 @default.
• W2138659763 cites W2117372576 @default.
• W2138659763 cites W2118022637 @default.
• W2138659763 cites W2122047873 @default.
• W2138659763 cites W2127058752 @default.
• W2138659763 cites W2128201662 @default.
• W2138659763 cites W2131397858 @default.
• W2138659763 cites W2132799109 @default.
• W2138659763 cites W2134647722 @default.
• W2138659763 cites W2135960212 @default.
• W2138659763 cites W2137213267 @default.
• W2138659763 cites W2139682729 @default.
• W2138659763 cites W2140134973 @default.
• W2138659763 cites W2140686574 @default.
• W2138659763 cites W2152286478 @default.
• W2138659763 cites W2163656669 @default.
• W2138659763 cites W2164257432 @default.
• W2138659763 cites W2170549062 @default.
• W2138659763 cites W2321972685 @default.
• W2138659763 cites W2332995388 @default.
• W2138659763 cites W2334809128 @default.
• W2138659763 cites W2431248070 @default.

• next