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- W2138703353 abstract "To extend the knowledge of triple bonding between group 6 transition metal and heavier group 14 elements, the structural and bonding aspects of (<TEX>$η^5-C_5H_5$</TEX>)<TEX>$(CO)_2$</TEX>M≡ER (M = Cr, Mo, W; E = Si, Ge, Sn, Pb) are investigated by hybrid density functional calculations at the B3PW91 level. Substituent effects are also investigated with R = H, Me, <TEX>$SiH_3$</TEX>, Ph, <TEX>$C_6H_3-2,6-Ph_2$</TEX>, <TEX>$C_6H_3-2,6-(C_6H_2-2,4,6-Me_3)_2$</TEX>, and <TEX>$C_6H_3-2,6-(C_6H_2-2,4,6- iPr_3)_2$</TEX>." @default.
- W2138703353 created "2016-06-24" @default.
- W2138703353 date "2003-06-20" @default.
- W2138703353 modified "2023-10-04" @default.
- W2138703353 title "Theoretical Investigation of Triple Bonding between Transition Metal and Main Group Elements in (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)(CO)<sub>2</sub>M≡ER (M = Cr, Mo, W; E = Si, Ge, Sn, Pb; R = Terphenyl Groups)" @default.
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- W2138703353 doi "https://doi.org/10.5012/bkcs.2003.24.6.832" @default.
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