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• W2138750564 abstract "While an unequal population of rapidly interconverting left- and right-handed conformers of a helical oligomer can be detected by circular dichroism, precise quantification of a conformer ratio has not previously been achieved. We demonstrate, using a set of labeled peptide analogues, that simple analysis of peak separation in their (13)C NMR spectra at slow and fast exchange allows an accurate value for the ratio of helical conformers to be obtained. The method reports the ratio of conformers at the site of the label and can therefore be used to investigate local variations in helical conformational control." @default.
• W2138750564 created "2016-06-24" @default.
• W2138750564 creator A5016049642 @default.
• W2138750564 creator A5025694125 @default.
• W2138750564 creator A5079804629 @default.
• W2138750564 date "2011-02-25" @default.
• W2138750564 modified "2023-10-06" @default.
• W2138750564 title "Measuring Screw-Sense Preference in a Helical Oligomer by Comparison of ¹³C NMR Signal Separation at Slow and Fast Exchange" @default.
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• W2138750564 doi "https://doi.org/10.1021/ja1097034" @default.
• W2138750564 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21351795" @default.
• W2138750564 hasPublicationYear "2011" @default.
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