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• W2138832403 abstract "During the coupling reaction between 3-alkoxy-7-amino-4-chloroisocoumarin and N-acyl alanine dipeptide, an unexpected deamidation reaction was observed. The proposed mechanism for this reaction involved the formation of an imide intermediate which after cleavage led to the release of amino acid moiety. The described deamidation reaction represents the first chemical model involving a non-peptidic moiety, which mimics biological and chemical deamidation processes occurring in proteins or peptides incorporating an asparagine or a glutamine residue." @default.
• W2138832403 created "2016-06-24" @default.
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• W2138832403 date "2004-04-01" @default.
• W2138832403 modified "2023-09-25" @default.
• W2138832403 title "N-Acyl substituted 7-amino-4-chloroisocoumarin: A peptide degradation model via an imide mechanism" @default.
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• W2138832403 doi "https://doi.org/10.1016/j.bmcl.2004.01.030" @default.
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