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- W2138990261 abstract "Abstract Arenediazothiolates (Ar‐NN‐SR; R alkyl or aryl) undergo homolysis on heating. This follows from substituent and solvent effects on decomposition rates; product formation is interpretable on a homolytic basis. Substituent as well as solvent viscosity effects suggest that the primary step consists in the formation of a radical pair documentclass{article}pagestyle{empty}begin{document}[left({rm{Ar}-{rm N}_2^bullet+{rm RS}^bullet}right)]end{document} rather than multiple fission documentclass{article}pagestyle{empty}begin{document}[left({rm{Ar}-{rm N}_2^bullet+{rm RS}^bullet}right)]end{document} . In contrast to the situation at high concentration hardly any induced decomposition takes place at the low concentrations used for kinetics." @default.
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- W2138990261 date "1967-01-01" @default.
- W2138990261 modified "2023-10-18" @default.
- W2138990261 title "Sulfur compounds in free radical reactions. Part II: Thermal decomposition of arenediazothiolates" @default.
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- W2138990261 doi "https://doi.org/10.1002/recl.19670861014" @default.
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