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• W2139078553 abstract "Abstract The magnetic interactions between organic π-radicals adsorbed on 1D and 2D α-boron-nitride (α-BN) crystals are investigated theoretically. As in the case of analogous systems with graphite surfaces [N. Tyutyulkov, F. Dietz, K. Mullen, Chem. Phys. 255 (2000) 223], an intramolecular exchange interaction between the π-electrons within a narrow half-filled band occurs, with the main component from the Coulomb (Hund) exchange. Compared to graphite the values of the effective Heisenberg exchange integral are smaller in the case of α-BN. The energy spectrum, and the magnetic and thermodynamic characteristics of Ising models consisting of methyl radicals adsorbed on 1D and 2D α-BN surfaces are discussed based on the analytically solved equations." @default.
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• W2139078553 date "2000-12-01" @default.
• W2139078553 modified "2023-09-26" @default.
• W2139078553 title "Magnetic exchange interaction between π-electron radicals adsorbed on α-boron-nitride surfaces" @default.
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• W2139078553 doi "https://doi.org/10.1016/s0009-2614(00)01206-9" @default.
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