FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2139088320> ?p ?o ?g. }

• W2139088320 endingPage "1324" @default.
• W2139088320 startingPage "1307" @default.
• W2139088320 abstract "The behavior of the meniscus in a static gas-electrode–gas-electrolyte system has been studied to clarify the mechanism(s) involved in the electrochemical dissolution of gaseous reactants in porous electrodes. Concurrent optical and electrochemical measurements in a specially designed cell, constructed from Teflon and fused quartz, demonstrated conclusively that although metastable thin films could be produced on the electrode by immersion followed by slow draining under high potentials (i.e., &gt; 0.8 V with respect to the normal hydrogen electrode), these films broke down irreversibly at lower potentials, and were never observed to form spontaneously. The most stable configuration was a meniscus with a finite contact angle which was between 1° and 3°. On the basis of the observed geometry of the meniscus and a finite contact angle, a detailed second-order nonlinear nonhomogeneous differential equation of the form d2ηdx2 + F(x) dηdx + A[exp(kη) − exp(k2η)]G(x)[1 + B G(x) exp(k1η)] = 0, where F(x), G(x), A, B, k1, and k2 include only the pertinent experimental conditions (meniscus shape, exchange current, diffusion coefficient, etc.), was derived involving both concentration and activation polarization and the IR drop in the meniscus. This equation was solved numerically in complete form on a digital computer. The computed relations of current to potential were within 10% of the experimentally obtained ones for both H2 and O2 in 1N H2SO4 on Pt electrodes, without the inclusion of “calibrating” factors. The results of the computations show that the meniscus is effectively divided into three regions. In the first, near the tip, the reaction kinetics on the electrode surface is the primary limiting factor. The second region has mixed diffusion and activation limitation up to the zone where the meniscus is so thick that negligible additional currents can be drawn. This zone starts the third (inactive) region which extends down into the bulk of the solution. The experimental conditions (potential, gas pressures, etc.) determine the location of the boundaries of these regions and thus the over-all behavior of the meniscus. At moderate polarizations, over 90% of the current is produced within a very small (10−4–10−5 cm) distance from the meniscus tip." @default.
• W2139088320 created "2016-06-24" @default.
• W2139088320 creator A5033901197 @default.
• W2139088320 creator A5084006521 @default.
• W2139088320 date "1969-02-01" @default.
• W2139088320 modified "2023-10-14" @default.
• W2139088320 title "Effect of a Finite-Contact-Angle Meniscus on Kinetics in Porous Electrode Systems" @default.
• W2139088320 cites W1975980988 @default.
• W2139088320 cites W1984236393 @default.
• W2139088320 cites W1996764892 @default.
• W2139088320 cites W2009021887 @default.
• W2139088320 cites W2034332984 @default.
• W2139088320 cites W2041691585 @default.
• W2139088320 cites W2043067643 @default.
• W2139088320 cites W2067460412 @default.
• W2139088320 cites W2078316991 @default.
• W2139088320 cites W2159685643 @default.
• W2139088320 cites W2216037888 @default.
• W2139088320 doi "https://doi.org/10.1063/1.1671193" @default.
• W2139088320 hasPublicationYear "1969" @default.
• W2139088320 type Work @default.
• W2139088320 sameAs 2139088320 @default.
• W2139088320 citedByCount "41" @default.
• W2139088320 countsByYear W21390883202012 @default.
• W2139088320 countsByYear W21390883202014 @default.
• W2139088320 countsByYear W21390883202015 @default.
• W2139088320 countsByYear W21390883202016 @default.
• W2139088320 countsByYear W21390883202017 @default.
• W2139088320 countsByYear W21390883202018 @default.
• W2139088320 countsByYear W21390883202019 @default.
• W2139088320 countsByYear W21390883202020 @default.
• W2139088320 countsByYear W21390883202021 @default.
• W2139088320 countsByYear W21390883202023 @default.
• W2139088320 crossrefType "journal-article" @default.
• W2139088320 hasAuthorship W2139088320A5033901197 @default.
• W2139088320 hasAuthorship W2139088320A5084006521 @default.
• W2139088320 hasConcept C113196181 @default.
• W2139088320 hasConcept C120665830 @default.
• W2139088320 hasConcept C121332964 @default.
• W2139088320 hasConcept C147789679 @default.
• W2139088320 hasConcept C159985019 @default.
• W2139088320 hasConcept C17525397 @default.
• W2139088320 hasConcept C185592680 @default.
• W2139088320 hasConcept C189178095 @default.
• W2139088320 hasConcept C192562407 @default.
• W2139088320 hasConcept C205049153 @default.
• W2139088320 hasConcept C43617362 @default.
• W2139088320 hasConcept C61511704 @default.
• W2139088320 hasConcept C6556556 @default.
• W2139088320 hasConcept C68801617 @default.
• W2139088320 hasConceptScore W2139088320C113196181 @default.
• W2139088320 hasConceptScore W2139088320C120665830 @default.
• W2139088320 hasConceptScore W2139088320C121332964 @default.
• W2139088320 hasConceptScore W2139088320C147789679 @default.
• W2139088320 hasConceptScore W2139088320C159985019 @default.
• W2139088320 hasConceptScore W2139088320C17525397 @default.
• W2139088320 hasConceptScore W2139088320C185592680 @default.
• W2139088320 hasConceptScore W2139088320C189178095 @default.
• W2139088320 hasConceptScore W2139088320C192562407 @default.
• W2139088320 hasConceptScore W2139088320C205049153 @default.
• W2139088320 hasConceptScore W2139088320C43617362 @default.
• W2139088320 hasConceptScore W2139088320C61511704 @default.
• W2139088320 hasConceptScore W2139088320C6556556 @default.
• W2139088320 hasConceptScore W2139088320C68801617 @default.
• W2139088320 hasIssue "3" @default.
• W2139088320 hasLocation W21390883201 @default.
• W2139088320 hasOpenAccess W2139088320 @default.
• W2139088320 hasPrimaryLocation W21390883201 @default.
• W2139088320 hasRelatedWork W1979166407 @default.
• W2139088320 hasRelatedWork W2360036608 @default.
• W2139088320 hasRelatedWork W2473100202 @default.
• W2139088320 hasRelatedWork W2592882731 @default.
• W2139088320 hasRelatedWork W2954622210 @default.
• W2139088320 hasRelatedWork W3205687707 @default.
• W2139088320 hasRelatedWork W4225849863 @default.
• W2139088320 hasRelatedWork W4308629191 @default.
• W2139088320 hasRelatedWork W4313117201 @default.
• W2139088320 hasRelatedWork W2188541167 @default.
• W2139088320 hasVolume "50" @default.
• W2139088320 isParatext "false" @default.
• W2139088320 isRetracted "false" @default.
• W2139088320 magId "2139088320" @default.
• W2139088320 workType "article" @default.