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- W2139163056 abstract "Preliminary investigation is conducted to characterize the rapid thermal decomposition process of SPLA/RD-1333 lead azide. Four samples of SPLA/RD-1333 lead azide are drawn from a stockpile batch, which was originally manufactured in 1967 by Uniroyal Chemical Company. The samples are subjected to Differential Scanning Calorimetry (DSC) analysis at a constant heating rate of 10 o C/min. Direct integration of the DSC curves with the 1 st order Arrhenius kinetics assumption results in the activation energies of the decomposition process ranging from 360 to 620 kJ/mol, which are considerably higher than previously reported values for α-lead azide and RD-1333 grade lead azide. Correlating the micrographs of the samples with the activation energies indicate that the sample exhibiting the crystal structure that deviates notably from the standard formation has the lowest activation energy, while the sample whose crystal structure conforms to the standard formation has the highest activation energy." @default.
- W2139163056 created "2016-06-24" @default.
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- W2139163056 date "2010-01-04" @default.
- W2139163056 modified "2023-09-25" @default.
- W2139163056 title "Preliminary Investigation of SPLA/RD-1333 Lead Azide Thermal Decomposition Kinetics" @default.
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- W2139163056 doi "https://doi.org/10.2514/6.2010-335" @default.
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