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- W2139331353 abstract "Three new compounds, [Cu(bimb)]2(HPW12O40)·3H2O (1), (H2bimb)2SiW12O40 (2) and (H2bimb)3CoW12O40 (3) (bimb = 1,4-bis(imidazol-1-ylmethyl)biphenyl), have been synthesized under the same hydrothermal conditions. Structural characterizations by single-crystal X-ray diffraction show that compound 1 possesses a porous metal–organic pseudo-rotaxane framework in which [PW12O40]3−clusters are encapsulated, whereas compounds 2 and 3 are common supramolecular compounds. The distinct structure of compound 1 suggests that the porous framework may selectively encapsulate the polyoxometalate clusters, although the three polyoxometalate clusters have subtle structural differences. Catalytic photodegradation of organic dye RhB by compounds 1–3 has been studied." @default.
- W2139331353 created "2016-06-24" @default.
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- W2139331353 date "2011-01-01" @default.
- W2139331353 modified "2023-10-16" @default.
- W2139331353 title "Study of a hydrothermal reaction system of copper, imidazole and polyoxometalates: selective assembly of a 3D porous metal–organic pseudo-rotaxane framework and encapsulation of polyoxometalate clusters" @default.
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- W2139331353 doi "https://doi.org/10.1039/c1ce05648d" @default.
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