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• W2139500713 abstract "The fused 2-vinyl or 2-phenyl substituted cyclobutanones 4 undergo stereoselective ring openings by the action of alkoxide ions ( t- BuO − or MeO − ) to produce novel vicinally disubstituted cycloalkene derivatives 5 and 6 in moderate to high yields. The ring cleavage usually occurs with complete regioselectivity. The accessibility of γ,δ-unsaturated ester or acid derivatives makes this transformation a good supplementary method for the well-established Johnson–Claisen rearrangement." @default.
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• W2139500713 date "2012-04-26" @default.
• W2139500713 modified "2023-10-01" @default.
• W2139500713 title "Alkoxide-induced ring opening of bicyclic 2-vinylcyclobutanones: A convenient synthesis of 2-vinyl-substituted 3-cycloalkene-1-carboxylic acid esters" @default.
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• W2139500713 doi "https://doi.org/10.3762/bjoc.8.72" @default.
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