Matches in SemOpenAlex for { <https://semopenalex.org/work/W2139538434> ?p ?o ?g. }
- W2139538434 abstract "Abstract The reaction of [Ru3(CO)12] with the phosphorus chalcogenide ligands (EPR2)( E ′ PR 2 ′ )NH [E = E′ = S, R = Ph, R′ = Me (L1) and E = E′ = Se, R = R′ = Ph (L2)] produced the complexes [Ru3(μ2-H)(μ3-S){μ2-S,S,P′-(SPPh2)(PMe2)N}(CO)8] 1, [Ru3(μ2-H)(μ3-S){μ2-S,S,P′-(SPMe2)(PPh2)N}(CO)8] 2, [Ru3(μ3-S)2{μ2-P,P′-(Ph2P)(PMe2)NH}(CO)7] 3, [Ru4(μ4-S)2{μ2-P,P′-(Ph2P)(PMe2)NH}(CO)8(μ2-CO)] 4, [Ru3(μ2-H)(μ3-Se){μ2-Se,Se,P′-(SePPh2)(PPh2)N}(CO)8], 5, [Ru3(μ3-Se)2{μ2-P,P′-(PPh2)2NH}(CO)7] 6, and [Ru4(μ4-Se)2{μ2-P,P′-(PPh2)2NH}(CO)8(μ2-CO)] 7, indicating that cleavage of one of the P E bonds of the ligand is one of the first steps in the reaction, followed by the cleavage the remaining P E′ bond. The isostructural tellurium compound, [Ru4(μ4-Te)2{μ2-P,P′-(PPh2)2NH}(CO)8(μ2-CO)] 8, was also prepared through the reaction of [Ru3(CO)12] with elemental Te and (PPh2)2NH. When the monothio ligand (SPPh2)(OPPh2)NH (L3) was used, a mononuclear derivative, [Ru{(SPPh2)(OPPh2)N}2(CO)2] 9, was formed suggesting that the presence of an oxygen atom favors the breaking of the metal-metal bonds instead of that of the P O bond. All these Ru complexes were characterized by spectroscopic methods and the X-ray crystal structures of complexes 1, 2, 3, 6, 8 and 9 were determined, thus allowing comparison between similar compounds containing different donating chalcogen atoms." @default.
- W2139538434 created "2016-06-24" @default.
- W2139538434 creator A5006146514 @default.
- W2139538434 creator A5011775839 @default.
- W2139538434 creator A5017010674 @default.
- W2139538434 creator A5048321960 @default.
- W2139538434 creator A5056700383 @default.
- W2139538434 creator A5067056390 @default.
- W2139538434 date "2009-11-01" @default.
- W2139538434 modified "2023-10-17" @default.
- W2139538434 title "Reactivity of [Ru3(CO)12] towards (EPR2)()NH (R=Ph, Me; R′=Ph; E, E′=O, S, Se): 31P and 77Se NMR spectroscopic characterization and structural analysis of the complexes formed" @default.
- W2139538434 cites W1866042767 @default.
- W2139538434 cites W1969512195 @default.
- W2139538434 cites W1976666995 @default.
- W2139538434 cites W1978621590 @default.
- W2139538434 cites W1987788150 @default.
- W2139538434 cites W1995850984 @default.
- W2139538434 cites W2000609992 @default.
- W2139538434 cites W2007415086 @default.
- W2139538434 cites W2010074251 @default.
- W2139538434 cites W2020944567 @default.
- W2139538434 cites W2031445330 @default.
- W2139538434 cites W2034380424 @default.
- W2139538434 cites W2035156831 @default.
- W2139538434 cites W2039388464 @default.
- W2139538434 cites W2046193155 @default.
- W2139538434 cites W2050649628 @default.
- W2139538434 cites W2052643805 @default.
- W2139538434 cites W2074040690 @default.
- W2139538434 cites W2085240614 @default.
- W2139538434 cites W2088212529 @default.
- W2139538434 cites W2088558678 @default.
- W2139538434 cites W2119321687 @default.
- W2139538434 cites W2131350133 @default.
- W2139538434 cites W2133806794 @default.
- W2139538434 cites W2151544538 @default.
- W2139538434 cites W3137858265 @default.
- W2139538434 cites W575763660 @default.
- W2139538434 cites W63582364 @default.
- W2139538434 cites W652059799 @default.
- W2139538434 doi "https://doi.org/10.1016/j.poly.2009.08.026" @default.
- W2139538434 hasPublicationYear "2009" @default.
- W2139538434 type Work @default.
- W2139538434 sameAs 2139538434 @default.
- W2139538434 citedByCount "3" @default.
- W2139538434 countsByYear W21395384342013 @default.
- W2139538434 crossrefType "journal-article" @default.
- W2139538434 hasAuthorship W2139538434A5006146514 @default.
- W2139538434 hasAuthorship W2139538434A5011775839 @default.
- W2139538434 hasAuthorship W2139538434A5017010674 @default.
- W2139538434 hasAuthorship W2139538434A5048321960 @default.
- W2139538434 hasAuthorship W2139538434A5056700383 @default.
- W2139538434 hasAuthorship W2139538434A5067056390 @default.
- W2139538434 hasConcept C115624301 @default.
- W2139538434 hasConcept C116569031 @default.
- W2139538434 hasConcept C142724271 @default.
- W2139538434 hasConcept C155647269 @default.
- W2139538434 hasConcept C161790260 @default.
- W2139538434 hasConcept C170493617 @default.
- W2139538434 hasConcept C178790620 @default.
- W2139538434 hasConcept C179104552 @default.
- W2139538434 hasConcept C185592680 @default.
- W2139538434 hasConcept C204787440 @default.
- W2139538434 hasConcept C205188671 @default.
- W2139538434 hasConcept C2776910235 @default.
- W2139538434 hasConcept C3044715 @default.
- W2139538434 hasConcept C544153396 @default.
- W2139538434 hasConcept C549387045 @default.
- W2139538434 hasConcept C55493867 @default.
- W2139538434 hasConcept C71240020 @default.
- W2139538434 hasConcept C71924100 @default.
- W2139538434 hasConcept C8010536 @default.
- W2139538434 hasConceptScore W2139538434C115624301 @default.
- W2139538434 hasConceptScore W2139538434C116569031 @default.
- W2139538434 hasConceptScore W2139538434C142724271 @default.
- W2139538434 hasConceptScore W2139538434C155647269 @default.
- W2139538434 hasConceptScore W2139538434C161790260 @default.
- W2139538434 hasConceptScore W2139538434C170493617 @default.
- W2139538434 hasConceptScore W2139538434C178790620 @default.
- W2139538434 hasConceptScore W2139538434C179104552 @default.
- W2139538434 hasConceptScore W2139538434C185592680 @default.
- W2139538434 hasConceptScore W2139538434C204787440 @default.
- W2139538434 hasConceptScore W2139538434C205188671 @default.
- W2139538434 hasConceptScore W2139538434C2776910235 @default.
- W2139538434 hasConceptScore W2139538434C3044715 @default.
- W2139538434 hasConceptScore W2139538434C544153396 @default.
- W2139538434 hasConceptScore W2139538434C549387045 @default.
- W2139538434 hasConceptScore W2139538434C55493867 @default.
- W2139538434 hasConceptScore W2139538434C71240020 @default.
- W2139538434 hasConceptScore W2139538434C71924100 @default.
- W2139538434 hasConceptScore W2139538434C8010536 @default.
- W2139538434 hasLocation W21395384341 @default.
- W2139538434 hasOpenAccess W2139538434 @default.
- W2139538434 hasPrimaryLocation W21395384341 @default.
- W2139538434 hasRelatedWork W1566527355 @default.
- W2139538434 hasRelatedWork W1836220703 @default.
- W2139538434 hasRelatedWork W1963510035 @default.
- W2139538434 hasRelatedWork W1966602992 @default.
- W2139538434 hasRelatedWork W1978044033 @default.
- W2139538434 hasRelatedWork W1990114907 @default.