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- W2139845401 abstract "SUMMARY A system is described for the formation of sedoheptulose mono- phosphate from adenosine by supernatant solution of rat liver homogenate. The product was identified as sedoheptulose phos- phate after sedoheptulose (as sedoheptulosan) was isolated fol- lowing hydrolysis with phosphatase. Its resistance to the ac- 1. 2. 3. 6. 7. 8. 9. 10. tion of muscle aldolase strongly suggests a monophosphate ester probably at position 7. Its chemical and physical properties matched those of authentic sedoheptulosan monohydrate. The relative ability of rat tissues to accomplish this transformation is as follows: lung, spleen, kidney, liver, heart, brain, and blood he- molysates. Purine nucleosides were better substrates than pyrimidine nucleosides. Optimal conditions of pH, concentra- tion of substrate, phosphate, and enzyme have been studied. Heavy metals, glyceraldehyde, dihydroxyacetone, iodoacetate, and deoxynucleosides are strong inhibitors of this system. Two striking features of the nucleoside-sedoheptulose mono- phosphate transformation were its dependence and the apparent utilization of only 1 pentose molecule for each mole- cule of sedoheptulose monophosphate formed. REFERENCES" @default.
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- W2139845401 date "1959-05-01" @default.
- W2139845401 modified "2023-09-27" @default.
- W2139845401 title "Conversion of Nucleoside to Sedoheptulose Monophosphate by Rat Liver" @default.
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- W2139845401 doi "https://doi.org/10.1016/s0021-9258(18)98159-7" @default.
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