Matches in SemOpenAlex for { <https://semopenalex.org/work/W2139857729> ?p ?o ?g. }
- W2139857729 endingPage "1506" @default.
- W2139857729 startingPage "1501" @default.
- W2139857729 abstract "Heck coupling reaction of iodobenzene and styrene proceeds rapidly and selectively in supercritical water even without any catalyst in the presence of base. Both the choice of base and the reaction conditions had a significant effect on the conversion and the selectivity of the coupling products. The addition of a relatively mild base such as potassium acetate facilitated the cross-coupling reaction, while the hydrolysis of phenyl halide was favored in the presence of a strong base. The conversion and the yields of coupling products increased with increasing temperature, reaching a maximum at 650 K near the critical temperature of water, and then decreased as the temperature was further increased. Water density had a significant influence on the reaction rate, showing nearly 30% augmentation with a slight increase in density from 0.45 to 0.56 g cm(-3), but had less effect on the product selectivity. Two possibilities of the role of water responsible for the noncatalytic Heck coupling reaction in supercritical water, that is, ion and water-catalyzed mechanisms have been considered." @default.
- W2139857729 created "2016-06-24" @default.
- W2139857729 creator A5017693179 @default.
- W2139857729 creator A5054229279 @default.
- W2139857729 creator A5075965154 @default.
- W2139857729 creator A5091753442 @default.
- W2139857729 creator A5091831787 @default.
- W2139857729 date "2004-03-15" @default.
- W2139857729 modified "2023-10-18" @default.
- W2139857729 title "Heck Coupling Reaction of Iodobenzene and Styrene Using Supercritical Water in the Absence of a Catalyst" @default.
- W2139857729 cites W1652479681 @default.
- W2139857729 cites W1964725336 @default.
- W2139857729 cites W1965029823 @default.
- W2139857729 cites W1969678859 @default.
- W2139857729 cites W1982368556 @default.
- W2139857729 cites W1987110745 @default.
- W2139857729 cites W1988259381 @default.
- W2139857729 cites W1994120106 @default.
- W2139857729 cites W1995607517 @default.
- W2139857729 cites W1996991941 @default.
- W2139857729 cites W2010182691 @default.
- W2139857729 cites W2013302752 @default.
- W2139857729 cites W2016909548 @default.
- W2139857729 cites W2017301582 @default.
- W2139857729 cites W2019814715 @default.
- W2139857729 cites W2024063284 @default.
- W2139857729 cites W2030625127 @default.
- W2139857729 cites W2037673037 @default.
- W2139857729 cites W2038488514 @default.
- W2139857729 cites W2038599593 @default.
- W2139857729 cites W2044435357 @default.
- W2139857729 cites W2065087428 @default.
- W2139857729 cites W2065818082 @default.
- W2139857729 cites W2069031140 @default.
- W2139857729 cites W2069037623 @default.
- W2139857729 cites W2082662238 @default.
- W2139857729 cites W2084164339 @default.
- W2139857729 cites W2088115176 @default.
- W2139857729 cites W2094443079 @default.
- W2139857729 cites W2095003912 @default.
- W2139857729 cites W2096566201 @default.
- W2139857729 cites W2108931784 @default.
- W2139857729 cites W2112930393 @default.
- W2139857729 cites W2118513583 @default.
- W2139857729 cites W2125284409 @default.
- W2139857729 cites W2126214832 @default.
- W2139857729 cites W2137590866 @default.
- W2139857729 cites W2149474947 @default.
- W2139857729 cites W2950243448 @default.
- W2139857729 cites W4240434218 @default.
- W2139857729 cites W4244269763 @default.
- W2139857729 cites W4245932685 @default.
- W2139857729 doi "https://doi.org/10.1002/chem.200305542" @default.
- W2139857729 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15034894" @default.
- W2139857729 hasPublicationYear "2004" @default.
- W2139857729 type Work @default.
- W2139857729 sameAs 2139857729 @default.
- W2139857729 citedByCount "16" @default.
- W2139857729 countsByYear W21398577292013 @default.
- W2139857729 countsByYear W21398577292014 @default.
- W2139857729 countsByYear W21398577292017 @default.
- W2139857729 countsByYear W21398577292021 @default.
- W2139857729 countsByYear W21398577292022 @default.
- W2139857729 crossrefType "journal-article" @default.
- W2139857729 hasAuthorship W2139857729A5017693179 @default.
- W2139857729 hasAuthorship W2139857729A5054229279 @default.
- W2139857729 hasAuthorship W2139857729A5075965154 @default.
- W2139857729 hasAuthorship W2139857729A5091753442 @default.
- W2139857729 hasAuthorship W2139857729A5091831787 @default.
- W2139857729 hasConcept C118419359 @default.
- W2139857729 hasConcept C118792377 @default.
- W2139857729 hasConcept C134306372 @default.
- W2139857729 hasConcept C15920480 @default.
- W2139857729 hasConcept C161790260 @default.
- W2139857729 hasConcept C168896768 @default.
- W2139857729 hasConcept C171560689 @default.
- W2139857729 hasConcept C175113610 @default.
- W2139857729 hasConcept C178790620 @default.
- W2139857729 hasConcept C179104552 @default.
- W2139857729 hasConcept C185592680 @default.
- W2139857729 hasConcept C2776451764 @default.
- W2139857729 hasConcept C2777566558 @default.
- W2139857729 hasConcept C33923547 @default.
- W2139857729 hasConcept C42058472 @default.
- W2139857729 hasConcept C48424934 @default.
- W2139857729 hasConcept C502130503 @default.
- W2139857729 hasConcept C521977710 @default.
- W2139857729 hasConcept C75473681 @default.
- W2139857729 hasConceptScore W2139857729C118419359 @default.
- W2139857729 hasConceptScore W2139857729C118792377 @default.
- W2139857729 hasConceptScore W2139857729C134306372 @default.
- W2139857729 hasConceptScore W2139857729C15920480 @default.
- W2139857729 hasConceptScore W2139857729C161790260 @default.
- W2139857729 hasConceptScore W2139857729C168896768 @default.
- W2139857729 hasConceptScore W2139857729C171560689 @default.
- W2139857729 hasConceptScore W2139857729C175113610 @default.
- W2139857729 hasConceptScore W2139857729C178790620 @default.
- W2139857729 hasConceptScore W2139857729C179104552 @default.