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- W2140061566 abstract "The new ligand tris(3-(pyridin-2-yl)-1H-pyrazol-1-yl)methane (HC(3-Pypz)3, 1) has been synthesised by the reaction of 2-(1H-pyrazol-3-yl)pyridine with CHCl3 and Na2CO3 under phase- transfer conditions. The reaction of HC(3-Pypz)3 with Co(BF4)2·6 H2O leads to the formation of dinuclear bis(µ-hydroxo) cobalt(II) complex (Co2(µ-OH)2(HC(3-Pypz)3)2)(BF4)2·2MeOH (2). This complex was crystallographically characterised. It comprises a Co2(µ-OH)2 core with bridging hydroxide ligands. The tripodal tris-(3-(pyridine-2-yl)-1H-pyrazol-1-yl)methane ligands coordinate each cobalt atom with one bidentate arm, respectively. By this chelating and at the same time bridging coordination mode an octahedral coordination environment is formed." @default.
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- W2140061566 date "2012-03-10" @default.
- W2140061566 modified "2023-10-12" @default.
- W2140061566 title "Syntheses and characterisation of tris(3-(pyridin-2-yl)-1H-pyrazol-1-yl)methane and its bis(µ-hydroxo) dicobalt(II) complex" @default.
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- W2140061566 doi "https://doi.org/10.3998/ark.5550190.0013.324" @default.
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