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• W2140136306 abstract "CaMoO4 nanocakes with uniform size and morphology were prepared on a large scale via a room temperature reverse-microemulsion method. The products were characterized in detail by X-ray powder diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy. By establishing the relations between the thermodynamic functions of nano-CaMoO4 and bulk-CaMoO4 reaction systems, the equations for calculating the surface thermodynamic functions of nano-CaMoO4 were derived. Then, combined with in-situ microcalorimetry, the molar surface enthalpy, molar surface Gibbs free energy, and molar surface entropy of the prepared CaMoO4 nanocakes at 298.15 K were successfully obtained as (19.674 ± 0.017) kJ·mol−1, (619.704 ± 0.016) J·mol−1, and (63.908 ± 0.057) J·mol−1·K−1, respectively." @default.
• W2140136306 created "2016-06-24" @default.
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• W2140136306 date "2015-04-30" @default.
• W2140136306 modified "2023-09-27" @default.
• W2140136306 title "Synthesis and Surface Thermodynamic Functions of CaMoO4 Nanocakes" @default.
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• W2140136306 doi "https://doi.org/10.3390/e17052741" @default.
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