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- W2140193561 endingPage "10764" @default.
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- W2140193561 abstract "The reactivity of nucleophilic carbodiphosphorane (C(PPh3)2, 1) and carbodicarbene (C(C(NMe)2C6H4)2, 2) towards various dichlorophosphines has been explored. In most cases the expected carbone-for-chloride ligand exchange was observed. However, the use of MeN(PCl2)2 resulted in a unique P-N bond cleavage that, according to computational studies, occurred via an SN2'-like mechanism." @default.
- W2140193561 created "2016-06-24" @default.
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- W2140193561 date "2015-01-01" @default.
- W2140193561 modified "2023-10-14" @default.
- W2140193561 title "Extending the chemistry of carbones: P–N bond cleavage via an S<sub>N</sub>2′-like mechanism" @default.
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- W2140193561 doi "https://doi.org/10.1039/c5cc03194j" @default.
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