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• W2140257790 abstract "Abstract A novel three-dimensional, open-framework selenite [H2N(CH2)2NH2]0.5·CoSeO3 (1) has been hydrothermally synthesized and characterized by elemental analyses, IR spectrum, XPS spectrum, TG analysis and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, with a = 6.6018(14) Å, b = 9.2559(19) Å, c = 7.9097(16) Å, β = 113.56(3)°, V = 443.02(16) Å3, and Z = 4. Compound 1 exhibits an interesting three-dimensional open-framework structure constructed from unique {CoSeO3}n layers aggregated from double helical chains pillared by en ligands. Furthermore, the open framework of 1 possesses three types of one-dimensional channels, in which the triangular channel is particularly rare in covalently bonded microporous materials. Acknowledgement The authors thank the National Natural Science Foundation of China (20371011) for financial support." @default.
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• W2140257790 date "2006-03-01" @default.
• W2140257790 modified "2023-10-14" @default.
• W2140257790 title "Structural effects of lone-pair electrons: a novel three-dimensional, open-framework metal selenite constructed from {CoSeO₃}_n double helical chains linked via ethylenediamine pillars" @default.
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• W2140257790 doi "https://doi.org/10.1080/00958970500262296" @default.
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