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- W2140305110 abstract "The title dodecanuclear Mn complex, namely dodeca-μ 2 -acetato-κ 24 O : O ′-tetraaquatetra-μ 2 -nitrato-κ 8 O : O ′-tetra-μ 4 -oxido-octa-μ 3 -oxido-tetramanganese(IV)octamanganese(III) nitromethane tetrasolvate, [Mn 12 (CH 3 COO) 12 (NO 3 ) 4 O 12 (H 2 O) 4 ]·4CH 3 NO 2 , was synthesized by the reaction of Mn 2+ and Ce 4+ sources in nitromethane with an excess of acetic acid. This compound is distinct from the previously known single-molecule magnet [Mn 12 O 12 (O 2 CMe) 16 (H 2 O) 4 ], synthesized by Lis [ Acta Cryst. (1980), B 36 , 2042–2044]. It is the first Mn 12 -type molecule containing nitrate ligands to be directly synthesized without the use of a preformed cluster. Additionally, this molecule is distinct from all other known Mn 12 complexes due to intermolecular hydrogen bonds between the nitrate and water ligands, which give rise to a three-dimensional network. The complex is compared to other known Mn 12 molecules in terms of its structural parameters and symmetry." @default.
- W2140305110 created "2016-06-24" @default.
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- W2140305110 date "2015-02-14" @default.
- W2140305110 modified "2023-09-27" @default.
- W2140305110 title "[Mn<sub>12</sub>O<sub>12</sub>(O<sub>2</sub>CMe)<sub>12</sub>(NO<sub>3</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>4</sub>]: facile synthesis of a new type of Mn<sub>12</sub>complex" @default.
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- W2140305110 doi "https://doi.org/10.1107/s2053229615002326" @default.
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