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- W2140457905 abstract "The five-coordinated complexes [Ru(CO)Cl(HCCHR)(PPh3)2] (R = n-C3H7, CMe3, SiMe3, Ph) react with 3,5-dimethylpyrazole (Me2Hpz) to give the addition products [Ru(CO)Cl(HCCHR)(PPh3)2(Me2Hpz)]. The crystal structure of the complex with R = n-C3H7 has been determined by X-ray crystallography, which shows that the two phosphine molecules, the pyrazole and alkenyl ligands, and CO and Cl occupy trans-positions in a slightly octahedron. This simple addition reaction always occurs in CH2Cl2/EtOH, but in Et2O/EtOH there is a simultaneous transformation of the alkenyl to an alkynyl ligand in the case of the complex with R = Ph." @default.
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- W2140457905 date "1988-09-01" @default.
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- W2140457905 title "Addition reactions of alkenyl complexes [Ru(CO)Cl(HCCHR)(PPh3)2] (R = n-C3H7, CMe3, SiMe3, Ph) with 3,5-dimethylpyrazole. The crystal structure of [Ru(CO)Cl(HCCHC3H7)(PPh3)2(Me2Hpz)]" @default.
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- W2140457905 doi "https://doi.org/10.1016/0022-328x(88)83067-5" @default.
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