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• W2140463048 abstract "In the formation of chiral crystals, the tendency for twist in the orientation of neighboring molecules is incompatible with ordering into a lattice: Twist is expelled from planar layers at the expense of local strain. We report the ordered state of a neat material in which a local chiral structure is expressed as twisted layers, a state made possible by spatial limitation of layering to a periodic array of nanoscale filaments. Although made of achiral molecules, the layers in these filaments are twisted and rigorously homochiral—a broken symmetry. The precise structural definition achieved in filament self-assembly enables collective organization into arrays in which an additional broken symmetry—the appearance of macroscopic coherence of the filament twist—produces a liquid crystal phase of helically precessing layers." @default.
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• W2140463048 date "2009-07-23" @default.
• W2140463048 modified "2023-10-01" @default.
• W2140463048 title "Helical Nanofilament Phases" @default.
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• W2140463048 doi "https://doi.org/10.1126/science.1170027" @default.
• W2140463048 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19628864" @default.
• W2140463048 hasPublicationYear "2009" @default.
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