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• W2140499329 startingPage "7069" @default.
• W2140499329 abstract "Abstract A comprehensive, time‐resolved, energy‐dispersive X‐ray diffraction study of the uptake of liquid alcohols (methanol, ethanol, propan‐1‐ol and propan‐2‐ol) by the flexible metal‐organic framework solid MIL‐53(Fe)[H 2 O] is reported. In the case of the primary alcohols, a fluorinated version of the MIL‐53(Fe) host ( C 2/ c symmetry V ca. 1000 Å 3 ), in which a fraction of framework hydroxides are replaced by fluoride, shows uptake of alcohols to give initially a partially expanded phase ( C 2/ c symmetry , V ca. 1200 Å 3 ) followed by an expanded form of the material (either Imcm or Pnam symmetry , V ca. 1600 Å 3 ). In the case of methanol–water mixtures, the EDXRD data show that the partially open intermediate phase undergoes volume expansion during its existence, before switching to a fully open structure if concentrated methanol is used; analogous behaviour is seen if the initial guest is propan‐2‐ol, which then is replaced by pyridine, where a continuous shift of Bragg peaks within C 2/ c symmetry is observed. In contrast to the partially fluorinated materials, the purely hydroxylated host materials show little tendency to stabilise partially open forms of MIL‐53(Fe) with primary alcohols and the kinetics of guest introduction are markedly slower without the framework fluorination: this is exemplified by the exchange of water by propan‐2‐ol, where a partially open C 2/ c phase is formed in a step‐wise manner. Our study defines the various possible pathways of liquid‐phase uptake of molecular guests by flexible solid MIL‐53(Fe)." @default.
• W2140499329 created "2016-06-24" @default.
• W2140499329 creator A5037704422 @default.
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• W2140499329 creator A5084275683 @default.
• W2140499329 creator A5086404167 @default.
• W2140499329 date "2011-05-09" @default.
• W2140499329 modified "2023-10-18" @default.
• W2140499329 title "Uptake of Liquid Alcohols by the Flexible FeIII Metal-Organic Framework MIL-53 Observed by Time-Resolved In Situ X-ray Diffraction" @default.
• W2140499329 cites W1822092150 @default.
• W2140499329 cites W1965136658 @default.
• W2140499329 cites W1970048015 @default.
• W2140499329 cites W1974755705 @default.
• W2140499329 cites W1979681627 @default.
• W2140499329 cites W1982637132 @default.
• W2140499329 cites W1995810362 @default.
• W2140499329 cites W1999373361 @default.
• W2140499329 cites W2001081785 @default.
• W2140499329 cites W2004550299 @default.
• W2140499329 cites W2009839551 @default.
• W2140499329 cites W2010073078 @default.
• W2140499329 cites W2011543810 @default.
• W2140499329 cites W2020905508 @default.
• W2140499329 cites W2022145641 @default.
• W2140499329 cites W2022167379 @default.
• W2140499329 cites W2024041692 @default.
• W2140499329 cites W2024781188 @default.
• W2140499329 cites W2037408832 @default.
• W2140499329 cites W2040775977 @default.
• W2140499329 cites W2040995650 @default.
• W2140499329 cites W2045528289 @default.
• W2140499329 cites W2045862747 @default.
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• W2140499329 cites W2050388551 @default.
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• W2140499329 cites W2053504432 @default.
• W2140499329 cites W2053555648 @default.
• W2140499329 cites W2053769541 @default.
• W2140499329 cites W2057785071 @default.
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• W2140499329 cites W2088169749 @default.
• W2140499329 cites W2088771535 @default.
• W2140499329 cites W2092448491 @default.
• W2140499329 cites W2093182007 @default.
• W2140499329 cites W2094083873 @default.
• W2140499329 cites W2099486431 @default.
• W2140499329 cites W2102363490 @default.
• W2140499329 cites W2103829561 @default.
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• W2140499329 cites W2115764422 @default.
• W2140499329 cites W2118911588 @default.
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• W2140499329 cites W2141067506 @default.
• W2140499329 cites W2142681205 @default.
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• W2140499329 doi "https://doi.org/10.1002/chem.201003634" @default.
• W2140499329 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21557349" @default.
• W2140499329 hasPublicationYear "2011" @default.
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