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- W2140542015 abstract "Flowers of Calendula officinalis were incubated with mevalonic acid doubly labelled with 14C in position 2 and 3H in positions 2R, 2S, 4R or 5R,S and the [3H/14C] ratios determined in squalene β-sitosterol, stigmasterol, Δ7-sterols and stigmastan-3 β-ol. The results indicated that in the biosynthesis of these sterols: formation of the Δ7 double bond is associated with elimination of hydrogen from the 7β position, formation of the Δ5 double bond with elimination of hydrogens from the 5 and 6α positions, and formation of the Δ22 double bond with elimination of the 22-pro-S and 23 hydrogens. Demethylation in position 4 is associated with elimination of hydrogen from the 3α position whereas demethylation in position 14 occurs without hydrogen loss from position 15. Alkylation in position 24 is associated with hydrogen elimination from this position." @default.
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- W2140542015 date "1974-08-01" @default.
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- W2140542015 title "Stereospecificity of sterol biosynthesis in Calendula officinalis flowers" @default.
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- W2140542015 doi "https://doi.org/10.1016/0031-9422(74)80306-7" @default.
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