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- W2140608352 abstract "Abstract The solution and solid‐state structures of hexamethylphosphoramide (HMPA) adducts of tetrachlorosilane (SiCl 4 ) are discussed. In solution, the meridional and facial isomers of the hexa‐coordinate cationic complex 3 HMPA ⋅ SiCl 3 + Cl − ( 2 ) predominate at all HMPA concentrations, and are in equilibrium with the hexa‐coordinate neutral trans ‐ and cis ‐2 HMPA ⋅ SiCl 4 complexes ( 1 ), as well as the penta‐coordinate cationic cis ‐2 HMPA ⋅ SiCl 3 + Cl − ( 3 ). Single crystal X‐ray analyses are reported for the ionized mer ‐3 HMPA ⋅ SiCl 3 + HCl 2 − and the neutral trans ‐2 HMPA ⋅ SiCl 4 complexes." @default.
- W2140608352 created "2016-06-24" @default.
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- W2140608352 date "2007-12-17" @default.
- W2140608352 modified "2023-10-18" @default.
- W2140608352 title "Neutral and Cationic Phosphoramide Adducts of Silicon Tetrachloride: Synthesis and Characterization of Their Solution and Solid-State Structures" @default.
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- W2140608352 doi "https://doi.org/10.1002/chem.200701466" @default.
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