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- W2140663970 abstract "The mass spectra of a series of deuteriated polymethylbenzenes confirm and extend the model derived from labeled p-xylenes for the loss of a methyl radical under electron impact. A methyl group flanked by two methyls undergoes no exchange before being lost. But one adjacent to an unsubstituted position appears to exchange with the o-hydrogen atom via a methyl-methylene-methyl cycle. At least in p-xylene, reformation of the methyl group may well be concerted with its loss. A similarly concerted coupling of CH2 and H and loss of the resultant methyl group could account for an apparent inconsistency between the mass spectra of methyl alkyl and phenyl alkyl ketones." @default.
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- W2140663970 date "1969-12-01" @default.
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- W2140663970 title "Organic ions in the gas phase—XXIII: Loss of CH3 from polymethylbenzenes" @default.
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- W2140663970 doi "https://doi.org/10.1002/oms.1210021211" @default.
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