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• W2140931648 abstract "Complexes of the types Pt(L)Cl2, [Pt(L)(D2O)2](NO3)2, [Pt(L)(D2O)(NO3)](NO3), Pt(L)(OD)2, [Pt(L)(D2O)Cl]+ and Pt(L)(OD)Cl, where L = ethylenediamine, N,N-dimethylethylenediamine, N,N′-dimethylethylenediamine and N,N,N′,N′-tetramethylethylenediamine, were characterized mainly by 195Pt and 1H (high- and low-field) nuclear magnetic resonance. The NMR spectra were measured in D2O. The dichloro complexes showed a 195Pt resonance between −2355 and −2433 ppm (relative to Na2PtCl6) whereas the diaqua compounds absorbed at lower field from −1821 to −1977 ppm. The signals of the monoaqua-monochloro species were observed at intermediate field between −2030 and −2173 ppm. The dihydroxo complexes showed a resonance at lower field (about 100 ppm) than the diaqua compounds, whereas the monochloro-monohydroxo species absorbed at about 50 ppm from the monoaqua-monochloro species. The monoaqua-mononitrato compounds with only two ligands absorbed at about −20 ppm from the diaqua species. The high-field proton NMR spectra of the complexes were also measured. The 195Pt–1H coupling constants were obtained from the low-field proton NMR spectra." @default.
• W2140931648 created "2016-06-24" @default.
• W2140931648 creator A5038825466 @default.
• W2140931648 creator A5087854124 @default.
• W2140931648 date "1991-02-01" @default.
• W2140931648 modified "2023-10-11" @default.
• W2140931648 title "195Pt and1H NMR studies of platinum(II) complexes with ethylenediamine derivatives" @default.
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• W2140931648 doi "https://doi.org/10.1002/mrc.1260290205" @default.
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