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• W2140993449 startingPage "1728" @default.
• W2140993449 abstract "3,5-Bis(trimethylsilylethynyl)-4,4-difluoro-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacene [BODIPY(CCTMS)2] has been synthesized by coupling of 3,5-dibromo-4,4-difluoro-8-(4-tolyl)-4-bora-3a,4a-diaza-s-indacene with trimethylsilylacetylene under pd(0) coupling conditions. The BODIPY(CCTMS)2 was used as a selective colourimetric and fluorescent chemodosimeter for fluoride ion, following the F− ion induced cleavage of trimethylsilyl group, the protecting group of ethyne functionality by monitoring the changes in UV–vis and fluorescence properties. The dosimeter BODIPY(CCTMS)2 display clear changes in colour, absorption and emission bands selectively for F− ion over other anions such as Cl−, Br−, I−, ClO4− and HPO42−." @default.
• W2140993449 created "2016-06-24" @default.
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• W2140993449 date "2010-02-01" @default.
• W2140993449 modified "2023-10-11" @default.
• W2140993449 title "Boron–dipyrromethene based specific chemodosimeter for fluoride ion" @default.
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• W2140993449 doi "https://doi.org/10.1016/j.tet.2009.12.039" @default.
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