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- W2141015097 abstract "The effects of crystal field stabilization of Fe2+, Co2+, and Ni2+ on isothermal bulk moduli of divalent monoxides are investigated on a simple crystal field theory. The calculated bulk moduli of high-spin FeO, CoO, and NiO agree well with experimental data. The molar volumes and bulk moduli of low-spin MnO, FeO, and NiO are also calculated. The ionic radii of low-spin Mn2+, Fe2+, and Ni2+, calculated from the molar volumes, agree with Shannon and Prewitt's ( 1969) prediction. The bulk modulus of low-spin FeO is calculated to be 2.23–2.83 Mbar at zero pressure. The spin-pairing transition gives a lower bulk sound velocity/density ratio than polymorphic transitions of oxides and silicates. This indicates that the spinpairing transition in the lower mantle may favor a mean atomic weight of the lower mantle that is smaller than previous estimates where the effect of spin-pairing transitions were not taken into account." @default.
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- W2141015097 date "1978-04-10" @default.
- W2141015097 modified "2023-09-25" @default.
- W2141015097 title "Crystal field effect on bulk moduli of transition metal oxides" @default.
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- W2141015097 doi "https://doi.org/10.1029/jb083ib04p01852" @default.
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