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- W2141054631 abstract "Quite often some of the ligand atoms of a chelating agent are protonated while others simultaneously are attached to a metal cation. Metal-hydrogen-complexes of that kind have usually been neglected in the elucidation of the equilibria between the various metal ions and chelating ligands. A general method is described by which the concentration of these protonated metal complexes can be obtained. The method is applied to the six systems: Cd2+ and Malonate (= Mal2−), Cd2+ and Succinate (= Succ2−), Cd2+ and Trimethylenediamine (= Triam), Cd2+ and Tetramethylenediamine (= Tetram), Hg2+ and Tetramethylenediamine; Hg2+ and Pentamethylenediamine (= Pentam). The stability constants of the following complexes are given: CdMal, CdHMal+, Cd(Mal)22−, CdH(Mal)2−, Cd(HMal)2; CdSucc, CdHSucc2+, Cd(Succ)22−; CdTriam2+, CdHTriam3+; CdTetram2+, CdHTetram3+; HgTetram2+, HgHTetram3+, Hg(HTetram); CdPentam2+, CdHPentam3+, Cd(HPentam)24+." @default.
- W2141054631 created "2016-06-24" @default.
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- W2141054631 date "1962-01-01" @default.
- W2141054631 modified "2023-10-17" @default.
- W2141054631 title "Protonierte Metallkomplexe zweizähniger Liganden" @default.
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- W2141054631 doi "https://doi.org/10.1002/hlca.19620450419" @default.
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