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• W2141171845 abstract "A new-type chiral ligand, (S)-N-[2-(diphenylphosphino)naphthyl]-2-(pyrrolidinylmethyl)piperidine mimicking N–Ar axial chirality, has been developed. This chiral ligand was found to exhibit 99% ee with the use of (E)-1,3-diphenyl-2-propenyl acetate as the standard substrate, and achieved slightly better results than the Pfaltz and Trost ligands with the use of (E)-1-phenyl-3-trimethylsilyl-2-propenyl acetate as the substrate, in the palladium-catalyzed asymmetric allylic substitution." @default.
• W2141171845 created "2016-06-24" @default.
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• W2141171845 date "2002-06-01" @default.
• W2141171845 modified "2023-10-17" @default.
• W2141171845 title "An N–Ar axially chiral mimetic. A new approach to ligand design for asymmetric catalysis" @default.
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• W2141171845 doi "https://doi.org/10.1016/s0040-4020(02)00507-0" @default.
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