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- W2141293357 abstract "Transition Metal Stannyl Complexes, 4. — Palladium and Platinum Complexes with Chelatting Phosphinoalkylstannyl Ligands by Oxidative Addition of Sn—C Bonds Reaction of (Ph3P)4Pd with two equivalents of Ph2PCH2CH2-SnR3 (R = Ph, Me) gives the Pd(II) stannyl complexes trans-Pd(PPh2CH2CH2SnR2)2 (2) by oxidative addition of two Sn—R groups and elimination of R—R. Products corresponding to earlier steps of the reaction are obtained by the reaction of (Ph3P)2Pt(C2H4) with Ph2P(CH2)nSnR3 (n = 2, 3). The phenylderivatives Ph2P[CH2]nSnPh3 afford the Pt(II) complexes (Ph3P)(Ph)PtPPh2[CH2]nSnPh2 (3), in which the two phosphorus atoms are cis-configurated, while Ph2PCH2CH2SnMe3 gives the Pt(IV) complex cis,cis,cis-(Me)2Pt(PPh2CH2CH2SnMe2)2 (3) as stable product." @default.
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- W2141293357 date "1991-10-01" @default.
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- W2141293357 title "Übergangsmetall‐Stannyl‐Komplexe, 4 Palladium‐ und Platin‐Komplexe mit Phosphinoalkylstannyl‐Chelatliganden durch oxidative Addition von Sn—C‐Bindungen" @default.
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- W2141293357 doi "https://doi.org/10.1002/cber.19911241006" @default.
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