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- W2141391618 abstract "The translational and angular intensity dependence of CO2 produced from the reaction of CO with an initial oxygen coverage of 0.5 ML ≤ ΘO ≤ 1.6 ML on Rh(111) at a surface temperature of 450 K was measured. This range of coverages goes from only surface absorbed O to both adsorbed and selvedge absorbed O. The measured CO2 translational energy is independent of ΘO and is larger than steady-state experiments [Colonell et al. J. Chem. Phys. 1995, 103, 6677], which were done at lower O coverages, but follows the trend that higher ΘO leads to faster CO2. The angular dependence of the intensity is well-described by a sharply peaked function of the form I = a cosn(θ) + (1 – a) cos(θ), with a = 0.6 and n = 8.6. Again, this was consistent with the previous steady-state results. These observations point to a similar reaction geometry regardless of ΘO; the measured dynamical parameters are independent of whether or not some of the O is subsurface and suggest that absorbed oxygen in the selvedge acts only as a reservoir for replenishing reagent as it is consumed." @default.
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- W2141391618 date "2014-06-27" @default.
- W2141391618 modified "2023-10-18" @default.
- W2141391618 title "Comparison of the Surface and Subsurface Oxygen Reactivity and Dynamics with CO Adsorbed on Rh(111)" @default.
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- W2141391618 doi "https://doi.org/10.1021/jp504369z" @default.
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