Matches in SemOpenAlex for { <https://semopenalex.org/work/W2141411626> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2141411626 endingPage "370" @default.
- W2141411626 startingPage "350" @default.
- W2141411626 abstract "The observed abnormal behaviour of the electrolyte uptake in ion exchangers (see preceding paper by Glueckauf & Watts) is interpreted quantitatively on the basis of a widespread non-uniformity of distribution of the counter-ions. In the case fully treated in this paper, i.e. for an exchanger of mean molality of 4·17, the range of counter-ion concentrations is shown to extend from about 15 molal to 10 -4 molal. This non-uniformity must have significant effects on the variation of the ion exchange separation factor at different mol-fractions in the exchanger phase. It explains qualitatively the observed fact, that the separation factor is usually larger when the more strongly sorbed ion is present at low mol-fractions, and that this effect increases both with the mean molality of the exchanger, and with the magnitude of the separation factor. The wide non-uniformity also explains the observed variation of the diffusion coefficient of imbibed electrolyte with concentration. A new quantitative treatment is introduced for diffusion through widely non-uniform media. Full agreement between theory and experiment is obtained at high uptake concentrations. At low uptake concentrations, two curves are obtained from the theory, according to whether the low concentration regions in the exchanger are considered as ‘continuous’ or ‘disperse’. The observed data lying between these two calculated curves suggest a considerable ‘continuity’ for the low concentration regions. They indicate the existence of a ‘continuous’ network of submicroscopic aqueous fissures or channels of about 70 Å width, widening occasionally to as much as 2000 Å. The resulting electrical double layer effects in these fissures explain the wide continuous variation of counter-ion concentrations." @default.
- W2141411626 created "2016-06-24" @default.
- W2141411626 creator A5007345475 @default.
- W2141411626 date "1962-07-24" @default.
- W2141411626 modified "2023-10-16" @default.
- W2141411626 title "A new approach to ion exchange polymers" @default.
- W2141411626 cites W19351644 @default.
- W2141411626 cites W1973075235 @default.
- W2141411626 cites W1985261292 @default.
- W2141411626 cites W1986095206 @default.
- W2141411626 cites W2031803227 @default.
- W2141411626 cites W2033573333 @default.
- W2141411626 cites W2039687711 @default.
- W2141411626 cites W2049012346 @default.
- W2141411626 cites W2051278439 @default.
- W2141411626 cites W2118111596 @default.
- W2141411626 cites W2152318224 @default.
- W2141411626 cites W2313557235 @default.
- W2141411626 cites W2319186775 @default.
- W2141411626 cites W4238839805 @default.
- W2141411626 doi "https://doi.org/10.1098/rspa.1962.0146" @default.
- W2141411626 hasPublicationYear "1962" @default.
- W2141411626 type Work @default.
- W2141411626 sameAs 2141411626 @default.
- W2141411626 citedByCount "64" @default.
- W2141411626 countsByYear W21414116262012 @default.
- W2141411626 countsByYear W21414116262013 @default.
- W2141411626 countsByYear W21414116262014 @default.
- W2141411626 countsByYear W21414116262015 @default.
- W2141411626 countsByYear W21414116262016 @default.
- W2141411626 countsByYear W21414116262019 @default.
- W2141411626 countsByYear W21414116262020 @default.
- W2141411626 countsByYear W21414116262022 @default.
- W2141411626 crossrefType "journal-article" @default.
- W2141411626 hasAuthorship W2141411626A5007345475 @default.
- W2141411626 hasConcept C113196181 @default.
- W2141411626 hasConcept C117760992 @default.
- W2141411626 hasConcept C121332964 @default.
- W2141411626 hasConcept C145148216 @default.
- W2141411626 hasConcept C147789679 @default.
- W2141411626 hasConcept C16946580 @default.
- W2141411626 hasConcept C170961132 @default.
- W2141411626 hasConcept C17525397 @default.
- W2141411626 hasConcept C178790620 @default.
- W2141411626 hasConcept C184651966 @default.
- W2141411626 hasConcept C185592680 @default.
- W2141411626 hasConcept C43617362 @default.
- W2141411626 hasConcept C44280652 @default.
- W2141411626 hasConcept C68801617 @default.
- W2141411626 hasConcept C69357855 @default.
- W2141411626 hasConcept C97355855 @default.
- W2141411626 hasConceptScore W2141411626C113196181 @default.
- W2141411626 hasConceptScore W2141411626C117760992 @default.
- W2141411626 hasConceptScore W2141411626C121332964 @default.
- W2141411626 hasConceptScore W2141411626C145148216 @default.
- W2141411626 hasConceptScore W2141411626C147789679 @default.
- W2141411626 hasConceptScore W2141411626C16946580 @default.
- W2141411626 hasConceptScore W2141411626C170961132 @default.
- W2141411626 hasConceptScore W2141411626C17525397 @default.
- W2141411626 hasConceptScore W2141411626C178790620 @default.
- W2141411626 hasConceptScore W2141411626C184651966 @default.
- W2141411626 hasConceptScore W2141411626C185592680 @default.
- W2141411626 hasConceptScore W2141411626C43617362 @default.
- W2141411626 hasConceptScore W2141411626C44280652 @default.
- W2141411626 hasConceptScore W2141411626C68801617 @default.
- W2141411626 hasConceptScore W2141411626C69357855 @default.
- W2141411626 hasConceptScore W2141411626C97355855 @default.
- W2141411626 hasIssue "1334" @default.
- W2141411626 hasLocation W21414116261 @default.
- W2141411626 hasOpenAccess W2141411626 @default.
- W2141411626 hasPrimaryLocation W21414116261 @default.
- W2141411626 hasRelatedWork W1964374618 @default.
- W2141411626 hasRelatedWork W2023540731 @default.
- W2141411626 hasRelatedWork W2038087272 @default.
- W2141411626 hasRelatedWork W2038226210 @default.
- W2141411626 hasRelatedWork W2083645833 @default.
- W2141411626 hasRelatedWork W2085022148 @default.
- W2141411626 hasRelatedWork W2093436028 @default.
- W2141411626 hasRelatedWork W2155485534 @default.
- W2141411626 hasRelatedWork W4240675204 @default.
- W2141411626 hasRelatedWork W2036636792 @default.
- W2141411626 hasVolume "268" @default.
- W2141411626 isParatext "false" @default.
- W2141411626 isRetracted "false" @default.
- W2141411626 magId "2141411626" @default.
- W2141411626 workType "article" @default.