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- W2141442541 abstract "Abstract The direct electrophilic trifluoromethylation of silyl ketene imines (SKIs) with hypervalent iodine reagents leads to the formation of quaternary α‐trifluoromethyl nitriles in good yields. This new reaction has been carried out with a variety of substituted SKIs under solvent‐free conditions using a vanadium(IV) catalyst (5 mol %). The corresponding products may be transformed into useful organofluorine building blocks." @default.
- W2141442541 created "2016-06-24" @default.
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- W2141442541 date "2014-08-21" @default.
- W2141442541 modified "2023-10-18" @default.
- W2141442541 title "Vanadium-Catalyzed Solvent-Free Synthesis of Quaternary α-Trifluoromethyl Nitriles by Electrophilic Trifluoromethylation" @default.
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- W2141442541 doi "https://doi.org/10.1002/anie.201406181" @default.
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