Matches in SemOpenAlex for { <https://semopenalex.org/work/W2141497064> ?p ?o ?g. }
- W2141497064 endingPage "3999" @default.
- W2141497064 startingPage "3991" @default.
- W2141497064 abstract "The series of alkyl 4-[2-(perfluorooctyl)ethoxy]benzoates (F8-n) shows a systematic change of crystal structures depending on the length of the alkyl chain: separate packing of perfluorooctyl (Rf) and alkyl (Rh) chains from each other for shorter (n=2) and longer (n=11) members, alternate packing of Rf and Rh chains for middle (n=6,7) members, and an intermediate type of packing for n=4. Semiempirical MO calculations show slightly repulsive interactions between the Rf chains, and attractive ones between Rf and Rh chains and between Rh and the core of a molecular pair. It is concluded that fluorination determines the molecular shape of the crystal structures by making the chain rigid. It is confirmed that the interactions between Rf chains are small compared with those between other moieties and that they are forced to aggregate owing to the exclusion from other moieties. Thus, the effect is dependent on the geometries and intermolecular interactions of the other moieties." @default.
- W2141497064 created "2016-06-24" @default.
- W2141497064 creator A5006587454 @default.
- W2141497064 creator A5034117852 @default.
- W2141497064 creator A5050139081 @default.
- W2141497064 creator A5050637834 @default.
- W2141497064 creator A5060412731 @default.
- W2141497064 date "2004-08-12" @default.
- W2141497064 modified "2023-10-11" @default.
- W2141497064 title "The Effect of Fluorination: A Crystallographic and Computational Study of Mesogenic Alkyl 4-[2-(Perfluorooctyl)ethoxy]benzoates" @default.
- W2141497064 cites W135111055 @default.
- W2141497064 cites W1968148714 @default.
- W2141497064 cites W1985018467 @default.
- W2141497064 cites W1987507022 @default.
- W2141497064 cites W1989072614 @default.
- W2141497064 cites W1989494580 @default.
- W2141497064 cites W1989895758 @default.
- W2141497064 cites W1990617252 @default.
- W2141497064 cites W1993659080 @default.
- W2141497064 cites W1994174641 @default.
- W2141497064 cites W1999043089 @default.
- W2141497064 cites W2000616275 @default.
- W2141497064 cites W2001748151 @default.
- W2141497064 cites W2004272668 @default.
- W2141497064 cites W2004402290 @default.
- W2141497064 cites W2012839861 @default.
- W2141497064 cites W2017752395 @default.
- W2141497064 cites W2021396019 @default.
- W2141497064 cites W2024785053 @default.
- W2141497064 cites W2025169164 @default.
- W2141497064 cites W2030841140 @default.
- W2141497064 cites W2031307456 @default.
- W2141497064 cites W2035679934 @default.
- W2141497064 cites W2035860684 @default.
- W2141497064 cites W2039035437 @default.
- W2141497064 cites W2039668581 @default.
- W2141497064 cites W2049896802 @default.
- W2141497064 cites W2053425492 @default.
- W2141497064 cites W2067302659 @default.
- W2141497064 cites W2070236096 @default.
- W2141497064 cites W2080486546 @default.
- W2141497064 cites W2085441783 @default.
- W2141497064 cites W2100057450 @default.
- W2141497064 cites W2105243822 @default.
- W2141497064 cites W2119428985 @default.
- W2141497064 cites W2119995176 @default.
- W2141497064 cites W2129177088 @default.
- W2141497064 cites W2140051962 @default.
- W2141497064 cites W2144858576 @default.
- W2141497064 cites W2146597739 @default.
- W2141497064 cites W2152358033 @default.
- W2141497064 cites W2511128857 @default.
- W2141497064 cites W2950505680 @default.
- W2141497064 cites W3016919694 @default.
- W2141497064 cites W4246652142 @default.
- W2141497064 doi "https://doi.org/10.1002/chem.200400123" @default.
- W2141497064 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15317063" @default.
- W2141497064 hasPublicationYear "2004" @default.
- W2141497064 type Work @default.
- W2141497064 sameAs 2141497064 @default.
- W2141497064 citedByCount "26" @default.
- W2141497064 countsByYear W21414970642012 @default.
- W2141497064 countsByYear W21414970642014 @default.
- W2141497064 countsByYear W21414970642016 @default.
- W2141497064 countsByYear W21414970642017 @default.
- W2141497064 countsByYear W21414970642018 @default.
- W2141497064 countsByYear W21414970642019 @default.
- W2141497064 countsByYear W21414970642020 @default.
- W2141497064 countsByYear W21414970642022 @default.
- W2141497064 countsByYear W21414970642023 @default.
- W2141497064 crossrefType "journal-article" @default.
- W2141497064 hasAuthorship W2141497064A5006587454 @default.
- W2141497064 hasAuthorship W2141497064A5034117852 @default.
- W2141497064 hasAuthorship W2141497064A5050139081 @default.
- W2141497064 hasAuthorship W2141497064A5050637834 @default.
- W2141497064 hasAuthorship W2141497064A5060412731 @default.
- W2141497064 hasConcept C115624301 @default.
- W2141497064 hasConcept C13274807 @default.
- W2141497064 hasConcept C166950319 @default.
- W2141497064 hasConcept C178017875 @default.
- W2141497064 hasConcept C178790620 @default.
- W2141497064 hasConcept C185592680 @default.
- W2141497064 hasConcept C192562407 @default.
- W2141497064 hasConcept C199360897 @default.
- W2141497064 hasConcept C204921945 @default.
- W2141497064 hasConcept C2777538812 @default.
- W2141497064 hasConcept C2780263894 @default.
- W2141497064 hasConcept C2781285689 @default.
- W2141497064 hasConcept C2994273327 @default.
- W2141497064 hasConcept C32909587 @default.
- W2141497064 hasConcept C41008148 @default.
- W2141497064 hasConcept C49040817 @default.
- W2141497064 hasConcept C521977710 @default.
- W2141497064 hasConcept C71240020 @default.
- W2141497064 hasConcept C8010536 @default.
- W2141497064 hasConcept C90150868 @default.
- W2141497064 hasConceptScore W2141497064C115624301 @default.
- W2141497064 hasConceptScore W2141497064C13274807 @default.