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- W2141569773 abstract "[Ru(Me3tacn)(CF3CO2)2OH2]CF3CO2[478980-00-6] RuC15H23F9N3O7 (MW 629.22)InChI = 1S/C9H21N3.3C2HF3O2.H2O.Ru/c1-10-4-6-11(2)8-9-12(3)7-5-10;3*3-2(4,5)1(6)7;;/h4-9H2,1-3H3;3*(H,6,7);1H2;/q;;;;;+3/p-3InChIKey = DLGOOOPDBFGHOT-UHFFFAOYSA-Kcis-[RuVI(Me3tacn)(CF3CO2)O2]CIO4(catalyst for alkene epoxidation1, 2 and alcohol oxidation2, 3)Physical Data: a pale yellow microcrystalline solid.Solubility: insoluble in n-hexane, diethyl ether, dichloromethane, chloroform, and acetonitrile but slowly dissolves in methanol or ethanol to give a pale yellow solution.Analysis of Reagent Purity: elemental analysis and FAB-MS.Preparative Methods: prepared by refluxing [Ru(Me3tacn)Cl3]4 with CF3CO2Ag in aq CF3CO2H (eq 1).1 The resulting red solution was hot-filtered to remove the insoluble AgCl. Slow evaporation of the solvent afforded a pale-yellow microcrystalline solid that was collected on a frit, washed with ice-cold water, and dried in vacuo. (1)cis-[RuII(6,6′-Cl2bpy)2(OH2)2](CF3SO3)2[120596-51-2] RuC22H16F6Cl4N4O8S2 (MW 885.23)InChI = 1S/2C10H6Cl2N2.2CHF3O3S.2H2O.Ru/c2*11-9-5-1-3-7(13-9)8-4-2-6-10(12)14-8;2*2-1(3,4)8(5,6)7;;;/h2*1-6H;2*(H,5,6,7);2*1H2;/q;;;;;;+2/p-2InChIKey = RQDRTNNNZANCHF-UHFFFAOYSA-Lcis-[RuVI(6,6′-Cl2bpy)2O2](CIO4)2(catalyst for oxidation of alcohols5 and alkanes;5, 6 hydrogenation7, 8)Physical Data: a red crystalline solid.Solubility: soluble in acetonitrile and water.Analysis of Reagent Purity: 1H NMR spectra can be recorded using CD3CN as solvent. Elemental analysis, FAB-MS, and UV-visible spectroscopy (in H2O), and cyclic voltammetry can be used for characterization and purity analysis.Preparative Methods: prepared by heating a mixture of cis-[RuII(6,6′-Cl2bpy)2Cl2]·2H2O and CF3SO3Ag in water at 70 °C for 30 min (eq 2). The resulting red solution was filtered to remove the insoluble AgCl. Slow evaporation of the solvent provided a red crystalline solid. (2)" @default.
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- W2141569773 date "2013-04-22" @default.
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- W2141569773 title "Ruthenium Complex ofN,N′,N′-Trimethyl-1,4,7-triazacyclononane and Ruthenium Complex ofcis-Diaquabis (6,6′-Dichloro-2,2′-bipyridine)" @default.
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