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- W2141612213 abstract "Abstract The stereoselective synthesis of triphenylene ketals offers access to unique scaffolds. For a good performance in supramolecular applications an all ‐ syn orientation of the functional groups is essential. The oxidative trimerization of catechol ketals by molybdenum pentachloride or mixtures with titanium tetrachloride leads to a template‐directed formation. Several heterocyclic moieties are suitable for this transformation. A template‐directed isomerization of anti , anti , syn isomers to the desired C 3 ‐symmetric derivative was demonstrated in two cases." @default.
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- W2141612213 date "2011-02-21" @default.
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- W2141612213 title "Synthesis of all-syn Functionalized Triphenylene Ketals" @default.
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- W2141612213 doi "https://doi.org/10.1002/ejoc.201001699" @default.
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