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- W2141652364 abstract "The deposition of metal nanostructures (wires and particles) on a graphite surface from an aqueous electrolyte solution was induced by galvanic displacement, via the oxidation of insoluble crystals of a ferrocene derivative (either n-butyl ferrocene or decamethyl ferrocene) present on the same substrate. Micron-to-millimetre-scale crystallites of decamethyl ferrocene were deposited on the graphite surface by evaporation from a solution of a nonpolar solvent (1,2-dichloroethane). Immersion of this modified surface into a dilute solution of a metal ion (e.g., CuII, AgI, PdII, PtII and others) caused the deposition of metal nanoparticles at step edges present on the graphite surface. The reducing equivalents required for the metal deposition process are provided by oxidation of the ferrocene derivative on the surface, as directly evidenced by elemental analysis and chronoamperometric experimental data presented here." @default.
- W2141652364 created "2016-06-24" @default.
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- W2141652364 date "2004-12-06" @default.
- W2141652364 modified "2023-10-11" @default.
- W2141652364 title "Electrodeposition of Metal Nanostructures by Galvanic Displacement Powered with Insoluble Crystals of a Ferrocene Derivative" @default.
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- W2141652364 doi "https://doi.org/10.1002/cphc.200400298" @default.
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