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• W2141719662 abstract "The use of methane as a reactive gas dramatically increases the selectivity of the arc-discharge synthesis of M-Ti-carbide clusterfullerenes (M=Y, Nd, Gd, Dy, Er, Lu). Optimization of the process parameters allows the synthesis of Dy2TiC@C80-I and its facile isolation in a single chromatographic step. A new type of cluster with an endohedral acetylide unit, M2TiC2@C80, is discovered along with the second isomer of M2TiC@C80. Dy2TiC@C80-(I,II) and Dy2TiC2@C80-I are shown to be single-molecule magnets (SMM), but the presence of the second carbon atom in the cluster Dy2TiC2@C80 leads to substantially poorer SMM properties." @default.
• W2141719662 created "2016-06-24" @default.
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• W2141719662 date "2015-09-09" @default.
• W2141719662 modified "2023-10-07" @default.
• W2141719662 title "Methane as a Selectivity Booster in the Arc‐Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single‐Molecule Magnet Dy ₂ TiC@C ₈₀ and Its Congener Dy ₂ TiC ₂ @C ₈₀" @default.
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• W2141719662 doi "https://doi.org/10.1002/anie.201505870" @default.
• W2141719662 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4902133" @default.
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