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- W2141764073 abstract "Substrates with neutral leaving groups undergo unimolecular solvolysis in nonpolar solvents. Whereas t-alkyl substrates invariably solvolyze by a unimolecular mechanism, s-alkyl and primary alkyl substrates can undergo both uni and bimolecular reactions, and the bimolecular step can take place on either the substrate itself or on an intimate ion-molecule pair formed in either a pre-equilibrium or in a rate determining step. Study of reactions at borderlines indicates that the individual reaction types remain distinct and do not merge." @default.
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- W2141764073 title "Nucleophilic substitution at saturated carbon atoms. Mechanisms and mechanistic borderlines: Evidence from studies with neutral leaving groups" @default.
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- W2141764073 doi "https://doi.org/10.1002/poc.610010103" @default.
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