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• W2141810080 startingPage "2482" @default.
• W2141810080 abstract "A BN interphase has been deposited, by isothermal/isobaric chemical vapor infiltration (ICVI) from BF3─NH3, within a preform made from ex-polycarbosilane (ex-PCS) fibers, at about 1000°C. In a second step, the BN-treated preform was densified with SiC deposited from CH3SiCl3─H2 at about the same temperature. From a thermodynamic standpoint, ex-PCS fibers could be regarded as unreactive vs the BF3─NH3 gas phase assuming they are coated with a thin layer of carbon or/and silica. The as-deposited interphase consists of turbostratic BN (N/B < 1) containing oxygen. The SiC infiltration acts as an annealing treatment: (i) the BN interphase becomes almost stoichiometric and free of oxygen; (ii) the fibers undergo a decomposition process yielding a SiO2/C layer at the BN/fiber interface. The weaker link in the interfacial sequence seems to be the BN/SiO2 interface. Deflection of microcracks arising from the failure of the matrix takes place at (or nearby) that particular interface." @default.
• W2141810080 created "2016-06-24" @default.
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• W2141810080 date "1991-10-01" @default.
• W2141810080 modified "2023-10-17" @default.
• W2141810080 title "Boron Nitride Interphase in Ceramic-Matrix Composites" @default.
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• W2141810080 doi "https://doi.org/10.1111/j.1151-2916.1991.tb06789.x" @default.
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