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- W2141842010 abstract "Abstract This paper describes the synthesis of unsymmetrically substituted phosphinous acids and phosphane oxides featuring at least one electron‐withdrawing pentafluoroethyl group. The presence of a diethylamino function as a protecting group allows a selective reaction of RClPNEt 2 (R=CF 3 , C 6 F 5 , C 6 H 5 ) with LiC 2 F 5 . On treatment with para ‐toluenesulfonic acid the isolated aminophosphanes R(C 2 F 5 )PNEt 2 are readily converted into the corresponding phosphinous acids or phosphane oxides, respectively. Investigation of the tautomeric equilibrium between oxide and acid tautomer revealed (CF 3 )(C 2 F 5 )POH as a stable phosphinous acid, whereas the pentafluorophenyl and phenyl derivatives constitute a solvent dependent equilibrium between the acid and the oxide tautomer." @default.
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- W2141842010 date "2014-05-19" @default.
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- W2141842010 title "Synthesis of Unsymmetrically Substituted Phosphane Oxides (R<sup>1</sup>R<sup>2</sup>P(O)H) and Phosphinous Acids (R<sup>1</sup>R<sup>2</sup>POH)" @default.
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- W2141842010 doi "https://doi.org/10.1002/chem.201402425" @default.
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