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- W2141869968 abstract "[reaction: see text] The enantioselective total syntheses of (+)-azimine and (+)-carpaine have been developed, starting with (S)-1,2,4-butanetriol as a single source of chirality. The key common feature in these syntheses involves stereoselective intramolecular hetero-Diels-Alder reaction of an acylnitroso compound. The critical macrocyclic dilactonization of the N-Cbz derivatives of azimic acid and carpamic acid was efficiently achieved by using the Yamguchi macrocyclization conditions." @default.
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- W2141869968 date "2004-02-24" @default.
- W2141869968 modified "2023-09-27" @default.
- W2141869968 title "Enantioselective Total Synthesis of (+)-Azimine and (+)-Carpaine." @default.
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- W2141869968 doi "https://doi.org/10.1002/chin.200408208" @default.
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